Transgranular stress corrosion cracking of 316 l stainless. Stress corrosion cracking of an austenitic stainless steel. On the stress corrosion cracking and hydrogen embrittlement. Based on the temperature, available moisture, stress level, and type of material used it was determined that the likely cause of failure was neutral ph, dilute chlorideinduced stress corrosion cracking. It follows the pattern of grains in the individual lattices of the material. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. The material studied is type 316l austenitic stainless steel, with cracking developing in conditions of controlled. Stress corrosion cracking of an austenitic stainless steel in. Chloride stress corrosion cracking cl scc all 300ss piping and pressure vessel components in any process units are susceptible cl scc cracking has occurred in watercooled condensers and in the process side of crude tower overhead condensers. Meletis and hochman 99 reported crystallographic tgscc for 99. As an analogy, in a wall of bricks, intergranular fracture would correspond to a fracture that takes place in the mortar that keeps the bricks. It is a growing crack formation in a corrosive atmosphere and highly chemically specific.
Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. Stress corrosion crack mechanisms can take various forms, such as intergranular scc, transgranular scc, or interdendritic scc. Stress corrosion cracking scc of austenitic 304 stainless steel in chloride environment is a common problem in industries. Simulation of inter and transgranular crack propagation.
Keywords strain, temperature, chloride stress corrosion cracking scc, corrosion fatigue, austenitic stainless steel, type 304l stainless steel, crack density. Chloride stress corrosion cracking clscc of stainless steel. Transgranular corrosion is a type of localized corrosion which occurs along cracks or faults across the crystals in metals and alloys. Wenman, mark, barton, james, trethewey, kenneth, jarman, sean, and chardtuckey, paul. When alloyed with oxygen or aluminum, transgranular stresscorrosion cracking can be induced in laboratory tests in seawater and. The cycle of scc crack growth is normally modeled as a fourstage process as shown in figure 45. Branched, brittle cracks were observed in the failure region and exhibited transgranular propagation. Stress corrosion cracking can proceed in one of two ways. The importance of a conjoint action of corrosion and stress as well as the nature of. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0. Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Commercial titanium can suffer intergranular stresscorrosion cracking see stress corrosion cracking in methanolic environments and red fuming nitric acid but otherwise it is immune to failure.
It has been reported that the environmentalfracture is discontinuous at the micron scale 4. Transgranular cracking is a key characteristic of chloride induced stress corrosion cracking in austenitic stainless steels. Metalenvironment combinations susceptible to cracking are specific. The cracking was determined to be classic branched transgranular stress corrosion cracking scc which is common in stainless steel.
Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Rus sian investigators reported that chlorides, a common contaminant in concentrated caustic, do not aggravate scc and may even play an inhibitive role. The socalled nuclear grades, such as 304l, contain low levels of c and are therefore hard to sensitise, which is a major problem with high c grades, and these low c grades mainly fail by transgranular scc. Chloride stress corrosion cracking inspectioneering. Tscc transgranular stress corrosion cracking acronymattic. The micrograph on the left x300 illustrates scc in a 316 stainless steel chemical processing piping system. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Stress corrosion cracking the international institute of. Nickelchromiummolybdenum alloys the main drawbacks of stainless steels is that these alloys are sensitive to chloride induced localized attack like pitting and crevice attack and stress corrosion cracking. Alloy 600 n06600, ni15% cr8% fe is satisfactory in hot caustic service. Stress corrosion cracking scc refers to the cracking of a material caused by the. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions. The more commonly seen transgranular fracture, occurs when the crack grows through the material grains.
Transgranular scc the cracks which run through the individual grains called as transgranular stress corrosion cracking as shown in the following figures. Intergranular stress corrosion cracking in inconel heat exchanger tube with the crack. In the hydroiodic acid at temperatures exceeding 177oc, alloy b2 was sensitive to transgranular stress corrosion cracking. The mechanism for igscc of pipeline steels apix65 is based on the presence of hydroxyl ions at the steelelectrolyte interface, which are formed by the applied cathodic current to protect the structure 71.
The initiation and propagation of chlorideinduced transgranular stresscorrosion cracking tgscc of 304l austenitic stainless steel under atmospheric conditions. The initiation and propagation of chlorideinduced transgranular. Finite element modelling of transgranular chloride stress corrosion cracking in 304l austenitic stainless steel. Both of type 304 and type 316 stainless steels showed quite similar. This is, of course, a very complex question for a forum like this. Intergranular and transgranular stress corrosion cracking. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization. The original 1997 cepa stress corrosion cracking recommended practices hereafter referred to as the practices were prepared and made.
Based on the temperature, available moisture, stress level, and type of material used it was determined that the likely cause of failure was neutral ph, dilute chloride induced stress corrosion cracking. Transgranular stress corrosion cracking an overview. Scc in a 316 stainless steel chemical processing piping system. The project aimed to determine whether grain boundary engineering gbe, through thermomechanical processing, could improve resistance to transgranular chloride stress corrosion crack nucleation in austenitic stainless steels. Identification of scc visual identification prior to failure is difficult due to the typical tightness of stresscorrosion cracks. Stress corrosion cracking scc of austenitic stainless steels has been a known failure mode for more than 80 years and it continues to be a major cause of. Mechanistic differences in transgranular and intergranular. Transgranular stress corrosion cracking of 304l stainless.
Chloride stress corrosion cracking clscc is one of the most common reasons why. Stress corrosion cracking facts and how to reduce the risk. Plastic deformation because of slip, the process by which a dislocation moves in response to shear stresses, contributes to ductile fracture through crack propagation across the grain boundaries transgranular. The effect of cold work cw has long been known to have a detrimental effect on scc performance of a stainless steel component. The initiation and propagation of chloride induced transgranular stresscorrosion cracking tgscc of 304l austenitic stainless steel under atmospheric conditions. Stress corrosion cracking scc may be defined as the delayed failure of alloys by cracking when exposed to certain environments in the presence of a static tensile stress. It often progresses quickly and can impact materials in different ways from dry cracking to catastrophic failure. Intergranular and transgranular stress corrosion cracking of. There are, consequently, a number of approaches that we can use to prevent scc, or at least to give an acceptable lifetime. Chloride stress corrosion cracking in austenitic stainless steel. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion.
A metallurgical investigation confirmed the mode of cracking to be intergranular as well as transgranular unlike conventional chloride cracking, which is primarily. Chlorideinduced transgranular stress corrosion cracking of. Intergranular stress corrosion cracking igscc is more common than transgranular scc. Typical appearance of chloride stress corrosion cracking. A limited number of tests were also performed on polycrystals in the chloride media and also in acidified 1 m na2so4. The scc and fatigue data for c465h950 in nacl environments in figs. In 28,29,30, the tests are performed under prescribed strain rate. A study on stress corrosion cracking of austenitic. Stresscorrosion cracking can result in catastrophic failure, often without any prior warning. A corrosive medium especially chloridebearing or hydrogensulphide h 2 s media. The traditional engineering view is that transgranular clscc does not.
Ods 304 alloys are found to be more resistant to scc than the commercial aisi 304 steels. This means that all environments do not cause scc on all of the alloys. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Table 2 lists several alloyenvironment com binations and the films that may form at the crack tip. The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks. Chloride stress corrosion cracking in austenitic stainless steel is. Stresscorrosion cracking scc of austenitic stainless steels has been a problem in the nuclear industry for many years. One of the most accepted mechanisms of stress corrosion cracking scc i.
For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Chloride stress corrosion cracking in austentic hse. Transgranular stresscorrosion cracking t scc in disordered copper25 at. A lowpower hand lens will greatly aid determination. Stress corrosion cracking damages intechopen booksfailureanalysisstresscorrosioncrackingdamages. Stress corrosion cracking international institute of. Stress corrosion cracking behavior of nickel base alloys. The interaction of corrosion fatigue and stresscorrosion. Intergranular fracture occurs when a crack propagates along the grain boundaries of a material, usually when these grain boundaries are weakened. Proceedings of the asme 2008 pressure vessels and piping conference.
Abstract the anodic reaction within the transgranular stress corrosion crack of 188 stainless steel in boiling mgcl2 was studied under the open circuit condition at constant tensile speeds. Chlorideinduced stress corrosion cracking of oxide. The penetration appears to be an oxidized scc crack. Controlling stress corrosion cracking scc in order for scc to occur, we require a susceptible material, an environment that will cause cracking of that material and a high enough stress or stress intensity factor. The stress corrosion cracking scc behavior of oxidedispersionstrengthened ods 304 austenitic steels has been investigatedinachloriderichaqueousenvironmentat143c. There are several types of stress corrosion cracking scc, for example, chlorideinduced scc and h 2 sinduced scc. It can lead to unexpected sudden failure of normally ductile metals. First, is the plateau in fatigue crack growth rates fig. Under a constant tensile load of 177 mpa, the crack growth rate in ods 304 steels is. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. Stress corrosion cracking is the cracking of a susceptible metal under the mixed influence of a tensile stress either residual or applied in a corrosive environment 46. Chloride stress corrosion cracking in austenitic stainless. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature.
Finite element modelling of transgranular chloride stress. Susceptibility to stress corrosion cracking of 254smo ss. Chloride stress corrosion cracking cl scc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. The phenomenon of scc stresscorrosion cracking is a delayed failure process. Transgranular scc hereafter referred to as scc on buried, highpressure. The micrograph below x300 illustrates scc in a 316 stainless steel chemical processing piping system. I have observed transgranular stress corrosion cracking in a coal injection lance pipe made of 309s grade of austenitic stainless steel. Austenitic stainless steels suffer from scc in chlorides, caustic, and. Potentiostatic polarization, constant deflection tests, and highresolution sem examination. Both intergranular and transgranular stress corrosion cracking are. Transgranular stress corrosion cracking tgscc is a typical fracture mode for the scc system of stainless steels in chloride environments, characterized by riverlike fractographs 15.
This form of corrosion is controlled by maintaining. Sep 18, 2017 the scc and fatigue data for c465h950 in nacl environments in figs. The stress corrosion cracking scc behavior of oxidedispersionstrengthened ods 304 austenitic steels has been investigated in a chloriderich aqueous environment at 143c. The influence of salt concentration, ph values and the addition of. Stress corrosion cracking scc is the formation and growth of crack through materials subjected to tensile stress and a specific corrosive medium. Figure 17 reveals a second oxidized corrosion penetration with branchlike features.
A study on stress corrosion cracking of austenitic stainless. Chloride ion scc in stainless steel is transgranular, occurs at somewhat elevated temperatures typically above 150o f, and occurs under a tensile stress. Transgranular stresscorrosion cracking of disordered cu. Why is chloride stress corrosion cracking transgranular. Steel preheater tube metallurgical technologies, inc. The entire crack sides were not passive during the crack propagation. Transgranular article about transgranular by the free. Alloy 600 n06600, ni15% cr8% fe is satisfactory in hot. Conditions inside intergranular scc crack are not acidic. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small.
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